Tag: oniom ions
Harnessing triaryloxonium ions for aryne generation.Smith, O.; Hindson, M.; Sreenithya, A.; Tataru, V.; Paton, R. S.; Burton, J. W.; Smith, M. D. Nat. Synth. 2024, 3, 58–66
Control of stereogenic oxygen in a helically chiral oxonium ion.Smith, O.; Popescu, M. V.; Hindson, M. J.; Paton, R. S.; Burton, J. W.; Smith, M. D. Nature 2023, 615, 430–435
- C&EN news: This new molecule owes its chirality to oxygen alone
- Chemistry World: New example of molecular chirality discovered
- Phys.org: Chemists synthesize and characterize novel helically chiral oxonium ion with a stereogenic oxygen atom center
- OPRD Highlight
- SynFacts Highlight
Chan, H. S. S.; Nguyen, Q. N. N.; Paton, R. S.; Burton, J. W. J. Am. Chem. Soc. 2019, 141, 15951–15962
Phosphazene Catalyzed Addition to Electron-Deficient Alkynes: the Importance of Nonlinear Allenyl Intermediates Upon Stereoselectivity.Simón, L.; Paton, R. S. J. Org. Chem. 2017, 82, 3855–3863
Catalytic Enantioselective Synthesis of Indanes via Cation-Directed 5-Endo-Trig Cyclization.Johnston, C. P.; Kothari, A.; Sergeieva, T.; Okovytyy, S. I.; Jackson, K. E.; Paton, R. S.; Smith, M. D. Nat. Chem. 2015, 7, 171–177
Origins of Asymmetric Phosphazene Organocatalysis: Computations Reveal a Common Mechanism for Nitro- and Phospho-Aldol Additions.Simón, L.; Paton, R. S. J. Org. Chem. 2015, 80, 2756–2766
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